ATMP, Amino tris (methylene phosphonic acid) SDS MSDS of Manufacturers & Exporters
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ATMP, Amino tris (methylene phosphonic acid) CAS Number 6419-19-8
ATMP, Amino tris (methylene phosphonic acid) SDS Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet 14-Aug-22
1. PRODUCT AND COMPANY IDENTIFICATION
Product Name: ATMP Phosphonate Mixture.
CAS Number: 6419-19-8
EINECS EC Number: 229-146-5
Relevant uses and uses advised against (if any): Oil & Gas Wells and Industrial Use.
Suppliers: As per letterhead.
2. HAZARDS IDENTIFICATION
GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008
Metal Corrosion, Category 1
Eye Irritation, Category 2
Labeling according to GHS USA & Regulation (EC) No 1272/2008
GHS Label Elements
Irritant |
Signal Word: Warning
Hazard Statements:
H290: May cause corrosion to metals
H319: Causes eye Irritation.
Precautionary Statements:
P234 Keep only in original container.
P264 Wash --- thoroughly after handling.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338 If IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P315: Get immediate medical advice/attention.
P336: Thaw frosted parts with lukewarm water. Do not rub affected areas.
P337+P313 If eye irritation persists: get medical advice/attention.
P406 Store in corrosive resistant/... container with a resistant inner liner.
3. COMPOSITION / INFORMATION ON INGREDIENTS
Amino tris (methylene phosphonic acid): 48%-52%
CAS: 6419-19-8
EINECS EC Number: 229-146-5
4. FIRST AID MEASURES
Always seek medical attention after first aid measures are provided.
Eyes: Flush with water for at least 15 minutes. Provide medical assistance.
Skin: Remove contaminated clothes and rinse skin with plenty of water or shower.
Ingestion: Do NOT induce vomiting. If the person is conscious, give milk or water to dilute stomach contents. Repose. Medical attention. Do not attempt to give anything by mouth to an unconscious person.
If spontaneous vomiting occurs, keep head below hips to prevent aspiration and monitor respiration if there is difficulty.
Inhalation: If adverse exposure to vapors and / or aerosols, immediately remove the affected person from exposure and get immediate medical assistance victim. If breathing is difficult, give oxygen. If stops breathing, give artificial respiration.
5. FIRE FIGHTING MEASURES
Temperature Auto Ignition: Not available
Fire Fighting: Material will not burn. Containers can build up pressure if exposed to heat (fire). Use water spray to cool fire exposed surfaces and to protect personnel.
Special Information In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes.
6. ACCIDENTAL RELEASE MEASURES OR LOSSES
Personal precautions, protective equipment, environmental precautions and emergency procedures: Use personal protective equipments. Do not get into eyes, skin, and clothing. Do not breath vapors.
Methods and materials used for containment Cleanup procedures and Storage:
Water Spill: Prevent additional discharge of material, if possible, without danger. Warn occupants and downstream and danger areas downwind of corrosive release and ask everyone to stay away. Since this material sinks and is soluble, probably not recoverable. Notify authorities.
Land Spill: Prevent additional discharge of material, if possible, without danger. Warn occupants and areas downwind of the dangers of releasing corrosive and ask everyone to stay away. For small spills implement cleanup procedures. For large spills, proceed with cleaning procedures and, if in public area, advise the authorities.
Contain spilled liquid with sand or earth. Recover by pumping or with suitable absorbent.
7. HANDLING AND STORAGE
Precautions for safe handling: Keep container closed. Open and handle container with care. Store in cool, well ventilated place away from incompatible materials.
DO NOT pressurize, cut, heat, or weld containers.
DO NOT reuse empty containers without commercial cleaning or reconditioning.
Conditions for safe storage, including any incompatibilities: Corrosive to most metals including carbon steel, aluminum alloys and copper and copper alloys. Avoid contact with strong alkalis, lead to violent reactions with the evolution of heat. Avoid contact with strong alkalis, metal salts of sulfides and sulfites, which could release toxic gases. Also avoid contact with strong oxidizing agents.
Temperature of Storage: Environmental
Storage Pressure: Atmospheric.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
USA OSHA PEL: TWA 1 mg/m3; STEL 3 mg/m3.
USA ACGIH TLV: TWA 1 mg/m3; STEL 3 mg/m3.
We recommend that exposure lower levels are observed as reasonable worker protection.
Engineering Controls: Ventilation should be provided to control exposure of workers and prevent health risks, and if necessary to reduce, prevent and control the generation of aerosols.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Clear Pale-yellow Liquid.
Odor: Odorless
Odor threshold: Not available.
pH: <2
Relative density: 1.33
Boiling Point: 226F 108C
Freezing Point: Not available.
Flash point: Not available.
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation Rate: <1 (n-butyl acetate = 1)
Flammability (solid, gas): Not available.
Percent Volatile: 50 @ 77F or as specified in assay.
Partition coefficient: n-octanol/water: Not available.
Solubility in Water: Soluble
Viscosity: Not available.
10. STABILITY AND REACTIVITY
Stable: Yes
Hazardous Polymerization: Will not occur.
Conditions to Avoid: Contact with common metals produces flammable hydrogen gas.
Hazardous Decomposition Products: phosphines, CO, CO2 and nitrogen oxides
Incompatible Materials: Avoid contact with strong alkalis, lead to violent reactions with the evolution of heat. Avoid contact with metal salts of sulfides and sulfites, which could release toxic gases. Also avoid contact with strong oxidizing agents.
11. TOXICOLOGICAL INFO
ATMP:
Acute toxicity
LD50 Oral - rat - 2.100 mg/kg
LD50 Dermal - rabbit - > 6.310 mg/kg
Toxicity for reproduction: ATMP acid is not toxic for reproduction, based on rats three generation study.
Genotoxicity / Mutagenicity: Not classified either for mutagenicity or genotoxicity.
Carcinogenicity: This product (or any component in it of 0.1% or greater) is not listed by NTP, IARC, OSHA OR THE DEPARTMENT OF THE ENVIRONMENT as a carcinogen.
Developmental Toxicity: No information found.
Reproductive Effects: No information found.
12. ECOLOGICAL INFORMATION
Environmental Toxicity:
Toxicity to fish flow-through test LC50 - Oncorhynchus mykiss (rainbow trout) - 150 mg/l - 14 d.
Toxicity to daphnia and other aquatic invertebrates static test EC50 - Daphnia magna (Water flea) - 297 mg/l - 48 h.
Persistence and Degradability: No information available.
Mobility: No information available.
Bioaccumulation/ Accumulation: No information available.
Results of PBT and vPvB assessment: No data available for assessment.
13. DISPOSAL
Empty Container: "Empty" containers retain product residue (liquid and / or vapor) and can be dangerous. Empty drums should be completely drained, properly cover, and send immediately to a drum re-conditioner or should duly divest.
General Comments: Discarded products, as sold, is considered a hazardous waste. This material must be disposed of in accordance with local, state, and federal laws that allow the treatment of hazardous chemical waste.
14. TRANSPORT INFORMATION
DOT USA, TDG Canada & ADR/RID Europe: Not controlled.
IMDG/IMO & IATA/ICAO: Not controlled.
15. REGULATORY INFO
UNITED STATES
311/312 Hazard Category: Acute Health, Reactive. See section 2.
Section 16 - Additional Information
European Labeling in Accordance with EC Directives:
H290 = May cause corrosion to metals
H319 = Causes eye Irritation
Disclaimer:
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Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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