Selenium Glycinate or Selenium Amino Acid Chelate SDS MSDS of Manufacturers & Exporters
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Selenium Glycinate or Selenium Amino Acid Chelate CAS Number NA
Selenium Glycinate or Selenium Amino Acid Chelate SDS, Safety Data Sheet
MSDS, Material Safety Data Sheet 27-July-22
1. Product Identification
Product Name & Other Names: Selenium Glycinate or Selenium Amino Acid Chelate
CAS No.: Not available
Relevant uses and uses advised against (if any): Industrial use only.
Supplier: As per letterhead.
2. Hazards Identification
GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008
Acute toxicity, Oral Category 4, H302
Acute toxicity, dermal Category 4, H312
Acute toxicity, inhalation Category 4, H332
Hazardous to the aquatic environment, acute hazard Category 2, H401
Labeling according to Regulation (EC) No 1272/2008
GHS Label Elements
Irritant |
Signal Words: Warning
Hazard statements:
H302: Harmful if swallowed.
H312: Harmful in contact with skin.
H332: Harmful if inhaled.
H401: Toxic to aquatic life.
Precautionary statements:
P261: Avoid breathing dust/fume/gas/mist/vapors/spray.
P262: Do not get in eyes, on skin, or on clothing.
P264 Wash skin thoroughly after handling.
P270 Do not eat, drink, or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P273 Avoid release to the environment.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302+352: IF ON SKIN: Wash with soap and water.
P332+313: If skin irritation occurs: Get medical advice/attention.
P304+340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305+ P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P337+P313 If eye irritation persists: Get medical advice/ attention.
P330: Rinse mouth.
General comments on selenium chemicals:
Carcinogenic Effects: Classified 3 (Not classifiable for human.) by IARC [Sodium selenite].
Mutagenic Effects: Mutagenic for mammalian somatic cells. [Sodium selenite]. Mutagenic for bacteria and/or yeast. [Sodium selenite].
Teratogenic Effects: Classified POSSIBLE for human [Sodium selenite].
Developmental Toxicity: Classified Reproductive system/toxin/female, Reproductive system/toxin/male [POSSIBLE] [Sodium selenite].
The substance may be toxic to blood, kidneys, liver, skin, central nervous system (CNS). Repeated or prolonged exposure to the substance can produce target organs damage.
Inhalation: This material is a dust or may produce dust. May cause respiratory tract (nose, throat, airways), and mucous membrane irritation with coughing, sneezing, breathing difficulty and headache. Breathing small amounts of this material during normal handling is not likely to cause harmful effects. Breathing in large amounts of this material may be harmful. Prolonged or repeated inhalation of selenium dust may cause bronchitis.
Ingestion: Swallowing small amounts of this material during normal handling is not likely to cause harmful effects. Swallowing large amounts may be harmful. Over-ingestion of Selenium may cause gastrointestinal upset with nausea, vomiting, and diarrhea, garlic like odor of the breath and sweat, metallic taste. Over-ingestion of selenium may be harmful or fatal. While selenium in the diet is essential for proper nutrition, long-term ingestion of high amounts may cause gastrointestinal tract and nervous system disturbances (giddiness, lassitude, irritability), breathing difficulty (dyspnea), skin sores, and yellowish skin, pallor, loss of hair & nails and decayed or spotted teeth. In some individuals, nervous system effects may progress to numbness, convulsions, and paralysis. Overexposure may cause anemia, kidney damage, and liver damage. Acute selenium poisoning is potential lethal due to cardiac failure and/or pulmonary edema.
3. Composition/Information on Ingredients
Product Name & Other Names: Selenium Glycinate or Selenium Amino Acid Chelate
CAS No.: Not available.
4. First Aid Measures
Always seek medical attention after first aid measures are provided.
Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Give large amounts of water to drink. Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact: Check for and remove any contact lenses. Immediately flush eyes with running water for at least 15 minutes, keeping eyelids open. Cold water may be used. Get medical attention.
5. Fire Fighting Measures
Fire: Not classed as flammable. Slightly flammable to flammable in presence of heat.
Fire Extinguishing Media: Dry chemical, foam, or carbon dioxide. Do not use a solid stream of water. Water spray may be used to keep fire exposed containers cool.
Extinguishing Media Not recommended: Avoid using solid water jet as it may scatter the fire.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes. Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used.
6. Accidental Release Measures
Personal precautions, protective equipment, and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Ensure adequate ventilation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment cleanup procedures and Storage: Contain spilled material. Cover with an inert, non-combustible absorbent material, (e.g., sand, earth, diatomaceous earth, vermiculite). Keep away from heat. Keep away from sources of ignition. Do not touch spilled material. Use water spray to reduce vapors. Prevent entry into sewers, basements, or confined areas; dike if needed. Eliminate all ignition sources. Stop leak if without risk. Sweep and shovel and place in an appropriate waste disposal container. Keep in suitable, closed containers for disposal.
7. Handling and Storage
Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.).
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like oxidizing materials and acids.
8. Exposure Controls/Personal Protection
Airborne Exposure Limits: TWA: 10 (mg/m3). Consult local authorities for acceptable limits.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to the substance is apparent and engineering controls are not feasible, consult an industrial hygienist.
Skin Protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron, or coveralls, as appropriate, to prevent skin contact.
Eye Protection: Use chemical safety goggles and/or a full-face shield where splashing is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Handle in accordance with good industrial hygiene and safety practice.
9. Physical and Chemical Properties
Appearance: A fine, free flowing spray dried light-yellow to cream powder.
Odor: Not available.
Odor threshold: Not available.
pH: Not available.
Relative density: Not available.
Melting point/freezing point: Not available.
Initial boiling point and boiling range: Not available.
Flash point: Not available.
Auto-ignition temperature: No information found.
Decomposition temperature: No information found.
Upper/lower flammability or explosive limits: No information found.
Vapor pressure: No information found.
Vapor density: No information found.
Evaporation rate: No information found.
Flammability (solid, gas): No information found.
Partition coefficient: n-octanol/water: No information found.
Solubility(ies): Soluble in water.
Viscosity: No information found.
10. Stability and Reactivity
Stability: Stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: Carbon dioxide, carbon monoxide, nitrogen oxides, selenium oxides and fumes may form when heated to decomposition.
Hazardous Polymerization: None reported.
Incompatibilities: Acids, oxidizing agents.
Conditions to Avoid: Heat, flames, dust generation, ignition sources and incompatibles.
11. Toxicological Information
LD50 Oral – Rat: Not available.
Carcinogenic Effects: Classified 3 (Not classifiable for human.) by IARC [Sodium selenite].
Mutagenic Effects: Mutagenic for mammalian somatic cells. [Sodium selenite]. Mutagenic for bacteria and/or yeast. [Sodium selenite].
Teratogenic Effects: Classified POSSIBLE for human [Sodium selenite].
Developmental Toxicity: Classified Reproductive system/toxin/female, Reproductive system/toxin/male [POSSIBLE] [Sodium selenite].
12. Ecological Information
Results of PBT and vPvB assessment: No information found.
Toxicity to fish LC50 - Lepomis macrochirus (Bluegill): No information found.
Environmental Toxicity: The LC50/96-hour values for fish are from 10 to over 100 mg/l.
Persistence and Degradability: No information found.
Bioaccumulation/ Accumulation: No information found.
Mobility: No information found.
13. Disposal Considerations
Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility.
14. Transport Information
Land transport DOT USA, TDG Canada & ADR/RID Europe: Not controlled.
Sea Transport IMDG/IMO: Not controlled.
Air Transport IATA/ ICAO: Not controlled.
15. Regulatory Information
USA:
SARA 311/312: Please see section 2.
US California Proposition 65: Listed.
16. Other Information
DISCLAIMER: The information and recommendations set forth herein are presented in good faith and believed correct as of the date hereof. It is compiled from various sources, and it is not necessarily all inclusive nor fully adequate in every circumstance. In addition, these suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules, or insurance requirements applicable. This SDS MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a professionally trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose. This shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. In no case shall our company be liable to loss or damages by the product user.
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