Sodium Perborate Anhydrous Monohydrate Tetrahydrate SDS MSDS of Manufacturers & Exporters
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Sodium Perborate Anhydrous Monohydrate Tetrahydrate
CAS Number:
CAS Number 7632-04-4 or 11138-47-9 Anhydrous
CAS Number 10332-33-9 Monohydrate
CAS Number 10486-00-7Tetrahydrate
Sodium Perborate Tetrahydrate SDS, Safety Data Sheet
MSDS, Material Safety Data Sheet 06-July-22
1. Product Identification
Product Name & Other Names: Sodium Perborate or Tetrahydrate Perborax or Hydrate of Peroxometaborate.
CAS No.: 10486-00-7
EINECS: EC Number: 239-172-9
Molecular Weight: 153.86
Chemical Formula: NaBO3-4H2O
Relevant uses and uses advised against (if any): Industrial Manufacturing.
Suppliers: As per letterhead.
2. Hazards Identification
GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008
Oxidizing solids Category 3, (H272)
Acute toxicity, Oral Category 4, (H302)
Serious eye damage Category 1, (H318)
Acute toxicity, inhalation Category 3 (H331)
Specific target organ toxicity - single exposure Category 3, (H335)
Reproductive toxicity Category 1B, (H360)
Labelling according to Regulation (EC) No 1272/2008
GHS Label Elements
Oxidizing Solid |
GHS Label Elements
Health Hazard |
GHS Label Elements
Toxic |
GHS Label Elements
Corrosive |
Signal word: Danger
Hazard statements:
H272 May intensify fire; oxidizer.
H302 Harmful if swallowed.
H318 Causes serious eye damage.
H331 Toxic if inhaled.
H335 May cause respiratory irritation.
H360 May damage fertility or the unborn child.
Precautionary statements:
P201 Obtain special instructions before use.
P202: Do not handle until all safety precautions have been read and understood.
P210: Keep away from heat/sparks/open flames/hot surfaces – No smoking.
P220 Keep/Store away from clothing/ combustible materials.
P221: Take any precaution to avoid mixing with combustibles.
P261 Avoid breathing dust/ fume/ gas/ mist/ vapors/ spray.
P264: Wash --- thoroughly after handling.
P270: Do not eat, drink, or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/ eye protection/ face protection.
P304+340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P370+378: In case of fire: Use Water spray, Foam for extinction.
P301+312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P308+313: IF exposed or concerned: Get medical advice/attention.
3. Composition/Information on Ingredients
Product Name & Other Names: Sodium Perborate or Tetrahydrate Perborax or Hydrate of Peroxometaborate.
CAS No.: 10486-00-7
EINECS: EC Number: 239-172-9
4. First Aid Measures
Always seek medical attention after first aid measures are provided.
Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.
5. Fire Fighting Measures
Flammability of the Product: Non-flammable but it is an oxidizer.
Products of Combustion: It emits toxic oxides of boron, sodium and fumes when heated to decomposition.
Fire: It is supporting fire as an oxidizer.
Explosion: Contact with oxidizable substances may cause explosion.
Fire Extinguishing Media: Water spray, Foam. Use means suitable for extinguishing surrounding fire. Avoid carbon dioxide and gas filled extinguisher.
Extinguishing Media Not recommended: None specified.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes. Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used.
6. Accidental Release Measures
Personal precautions, protective equipment, and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment cleanup procedures and Storage: Eliminate all sources of ignition. Do not let the product enter drains. Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and allow evacuating through the sanitary system if local laws permit.
7. Handling and Storage
Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool <32C, dry and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Do not leave the material container open. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like combustible substances, organic substances, reducing agents, powdered metals, strong bases, alcohols, phosphorous, anhydrides, halogens, acids, metal powders.
8. Exposure Controls/Personal Protection
Airborne Exposure Limits: None established. Limit.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full-face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.
9. Physical and Chemical Properties
Appearance: White crystals or powder.
Odor: None.
Odor threshold: Not available.
pH: 10 at 1% solution at 25 C (77F)
Relative density: Not available.
Melting Point: Decomposes at 60C
Initial boiling point and boiling range: Not available.
Flash point: Not available.
Auto-ignition temperature: No information found.
Decomposition temperature: No information found.
Upper/lower flammability or explosive limits: No information found.
Vapor pressure: No information found.
Vapor density: No information found.
Evaporation rate: No information found.
Flammability (solid, gas): No information found.
Partition coefficient: n-octanol/water: No information found.
Solubility: Soluble in water.
Viscosity: No information found.
Molecular Weight: 153.86
Chemical Formula: NaBO3-4H2O
10. Stability and Reactivity
Stability: It is stable under ordinary conditions of use and storage. It becomes unstable by heat and moisture.
Hazardous Decomposition Products: Oxygen, oxides of sodium, boron oxides and fumes.
Hazardous Polymerization: Will not occur.
Incompatibilities: Organic substances, Strong reducing agents, Powdered metals, Strong bases, Alcohols, phosphorous, Anhydrides, Halogens, Acids, Metal powders and Reducing agents.
Conditions to Avoid: Moisture, Heat, Incompatibles.
11. Toxicological Information
Toxicity to Animals:
ORAL (LD50): 1908 mg/kg (Rat) on anhydrous basis.
ORAL (LD50): 1060 mg/kg [Mouse] on anhydrous basis.
Intravenous (LD50 ): 600 mg/kg (Cat) on anhydrous basis.
Carcinogenic Effects: Not a reported carcinogen.
Mutagenic Effects: No information found.
Teratogenic Effects: No information found.
Developmental Toxicity: No information found.
12. Ecological Information
Environmental Toxicity:
LC50/96h: 51 mg/l (Brachydanio rerio) on anhydrous basis.
NOEC/48h: 8 mg/l (Daphnia magna) on anhydrous basis.
NOEC/96h: 25 mg/l (Brachydanio rerio) on anhydrous basis.
Results of PBT and vPvB assessment: This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
13. Disposal Considerations
Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility.
14. Transport Information
Land Transport DOT USA, TDG Canada & ADR/RID Europe
Shipping Name: OXIDIZING SOLID, N.O.S. (Sodium peroxometaborate tetrahydrate)
Hazard Class: 5.1; Packing Group: III
UN Number: UN1479
Sea Transport IMDG/IMO
Shipping Name: OXIDIZING SOLID, N.O.S. (Sodium peroxometaborate tetrahydrate)
Hazard Class: 5.1; Packing Group: III
UN Number: UN1479
Air Transport IATA/ICAO
Shipping Name: OXIDIZING SOLID, N.O.S. (Sodium peroxometaborate tetrahydrate)
Hazard Class: 5.1; Packing Group: III
UN Number: UN1479
15. Regulatory Information
USA:
SARA 311/312 Hazards: See section 2.
California Prop. 65 Components: This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.
16. Other Information
DISCLAIMER: The information and recommendations set forth herein (hereinafter "Information") are presented in good faith and believed correct as of the date hereof. It is compiled from various sources, and it is not necessarily all inclusive nor fully adequate in every circumstance. In addition, these suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules, or insurance requirements applicable. This SDS MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a professionally trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose. This shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. In no case shall our company be liable to loss or damages by the product user.
The MSDS-SDS Hazard Statement of Sodium Perborate Anhydrous Monohydrate:
Sodium Perborate Monohydrate Anhydrous SDS, Safety Data Sheet
MSDS, Material Safety Data Sheet 06-July-22
1. Product Identification
Product Name & Other Names: Sodium Perborate.
CAS No.: 10332-33-9 Monohydrate), 7632-04-4 or 11138-47-9 (Anhydrous)
EINECS: EC Number: 231-556-4 or 234-390-0 (Anhydrous, Monohydrate)
Molecular Weight: 81.82 Anhydrous, 99.81 Monohydrate
Chemical Formula: BNaO3 Anhydrous, BNaO3.H2O Monohydrate
Relevant uses and uses advised against (if any): Industrial Manufacturing.
Suppliers: As per letterhead.
2. Hazards Identification
GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008
Oxidizing solids Category 3, (H272)
Acute toxicity, Oral Category 4, (H302)
Serious eye damage Category 1, (H318)
Acute toxicity, inhalation Category 3 (H331)
Specific target organ toxicity - single exposure Category 3, (H335)
Reproductive toxicity Category 1B, (H360)
Labelling according to Regulation (EC) No 1272/2008
GHS Label Elements
Oxidizing Solid |
GHS Label Elements
Health Hazard |
GHS Label Elements
Toxic |
GHS Label Elements
Corrosive |
Signal word: Danger
Hazard statements:
H272 May intensify fire; oxidizer.
H302 Harmful if swallowed.
H318 Causes serious eye damage.
H331 Toxic if inhaled.
H335 May cause respiratory irritation.
H360 May damage fertility or the unborn child.
Precautionary statements:
P201 Obtain special instructions before use.
P202: Do not handle until all safety precautions have been read and understood.
P210: Keep away from heat/sparks/open flames/hot surfaces – No smoking.
P220 Keep/Store away from clothing/ combustible materials.
P221: Take any precaution to avoid mixing with combustibles.
P261 Avoid breathing dust/ fume/ gas/ mist/ vapors/ spray.
P264: Wash --- thoroughly after handling.
P270: Do not eat, drink, or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/ eye protection/ face protection.
P330: Rinse mouth.
P304+340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P370+378: In case of fire: Use Water spray, Foam for extinction.
P301+312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P308+313: IF exposed or concerned: Get medical advice/attention.
3. Composition/Information on Ingredients
Product Name & Other Names: Sodium Perborate.
CAS Number: 10332-33-9 (Monohydrate)
EINECS: EC Number: 231-556-4
4. First Aid Measures
Always seek medical attention after first aid measures are provided.
Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.
Note to Physician: Symptomatic and supportive treatment is recommended.
5. Fire Fighting Measures
Flammability of the Product: Non-flammable but it is an oxidizer.
Products of Combustion: It emits toxic oxides of boron, sodium and fumes when heated to decomposition.
Fire: Sodium Perborate is supporting fire as an oxidizer.
Explosion: Contact with oxidizable substances may cause explosion.
Fire Extinguishing Media: Water spray, Foam. Use means suitable for extinguishing surrounding fire. Avoid carbon dioxide and gas filled extinguisher.
Extinguishing Media Not recommended: None specified.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes. Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used.
6. Accidental Release Measures
Personal precautions, protective equipment, and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment cleanup procedures and Storage: Eliminate all sources of ignition. Do not let the product enter drains. Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and allow evacuating as per law.
7. Handling and Storage
Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Wear suitable protective clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool <32C, dry and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Do not leave the material container open. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like combustible substances, organic substances, reducing agents, powdered metals, strong bases, alcohols, phosphorous, anhydrides, halogens, acids, metal powders.
8. Exposure Controls/Personal Protection
Airborne Exposure Limits: None established. Limit.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full-face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.
9. Physical and Chemical Properties
Appearance: White crystals or powder.
Odor: None.
Odor threshold: Not available.
pH: 10 at 1% solution at 25 C (77F)
Relative density: 2.4 - 2.6
Melting Point: Decomposes at 60C
Initial boiling point and boiling range: Not available.
Flash point: Not available.
Auto-ignition temperature: No information found.
Decomposition temperature: No information found.
Upper/lower flammability or explosive limits: No information found.
Vapor pressure: No information found.
Vapor density: No information found.
Evaporation rate: No information found.
Flammability (solid, gas): No information found.
Partition coefficient: n-octanol/water: No information found.
Solubility: Soluble in water.
Viscosity: No information found.
Molecular Weight: 99.81
Molecular Formula: BNaO3- H2O
% Volatile by volume @ 21C (70F): 0
10. Stability and Reactivity
Stability: Sodium Perborate is stable under ordinary conditions of use and storage. It becomes unstable by heat and moisture.
Hazardous Decomposition Products: Oxygen, oxides of sodium, boron oxides and fumes.
Hazardous Polymerization: Will not occur.
Incompatibilities: Organic substances, Strong reducing agents, Powdered metals, Strong bases, Alcohols, phosphorous, Anhydrides, Halogens, Acids, Metal powders and Reducing agents.
Conditions to Avoid: Moisture, Heat, Incompatibles.
11. Toxicological Information
Toxicity to Animals:
ORAL (LD50): 1908 mg/kg (Rat).
ORAL (LD50): 1060 mg/kg [Mouse].
Intravenous (LD50 ): 600 mg/kg (Cat)
Carcinogenicity: No component of this product present at levels greater than or equal to 0.1% is identified as possible or confirmed human carcinogen by IARC, ACGIH, OSHA and NTP.
Teratogenic Effects: No information found.
Mutagenic Effects: No information found.
Developmental Toxicity: No information found.
Reproductive Effects: No information found.
12. Ecological Information
Environmental Toxicity:
LC50/96h: 51 mg/l (Brachydanio rerio)
NOEC/48h: 8 mg/l (Daphnia magna)
NOEC/96h: 25 mg/l (Brachydanio rerio).
Results of PBT and vPvB assessment: This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
13. Disposal Considerations
Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility.
14. Transport Information
Land Transport DOT USA, TDG Canada & ADR/RID Europe
Shipping Name: SODIUM PERBORATE MONOHYDRATE
Hazard Class: 5.1; Packing Group: III; Hazard Label: Oxidizer
UN Number: UN3377
Sea Transport IMDG/IMO
Shipping Name: SODIUM PERBORATE MONOHYDRATE
Hazard Class: 5.1; Packing Group: III; Hazard Label: Oxidizer
UN Number: UN3377
Marine pollutant: No
Air Transport IATA/ICAO
Shipping Name: SODIUM PERBORATE MONOHYDRATE
Hazard Class: 5.1; Packing Group: III; Hazard Label: Oxidizer
UN Number: UN3377
15. Regulatory Information
USA:
SARA 311/312 Hazards: See section 2.
California Prop. 65 Components: This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.
16. Other Information
DISCLAIMER: The information and recommendations set forth herein (hereinafter "Information") are presented in good faith and believed correct as of the date hereof. It is compiled from various sources, and it is not necessarily all inclusive nor fully adequate in every circumstance. In addition, these suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules, or insurance requirements applicable. This SDS MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a professionally trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose. This shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. In no case shall our company be liable to loss or damages by the product user.
Specifications of Sodium Perborate Tablets Crystals BP Ph Eur EP JP USP NF IP ACS Analytical Reagent FCC Food grade Manufacturers |
